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    埋藏条件下碳酸盐岩实验室溶蚀作用模拟的热力学模型与地质勘探方向——以陕甘宁盆地下奥陶统马家沟组第五段为例

    THERMODYNAMIC MODEL FOR EXPERIMENTAL SIMULATION OF DISSOLUTION OF THE CARBONATE ROCKS IN THE BURIAL ENVIRONMENTS:AN EXAMPLE FROM THE FIFTH MEMBER OF THE LOWER DEVONIAN MAJIAGOU FORMATION IN THE SHAANXI-GANSU-NINGXIA BASIN

    • 摘要: 陕甘宁盆地下奥陶统马家沟组五段为潮坪相碳酸盐岩夹蒸发盐沉积。马五段经历了多期复杂的成岩作用,其中溶蚀作用对马五段影响深刻。首次引用热力学理论对埋藏条件下碳酸盐岩溶蚀作用进行了理论分析和计算。其结果表明碳酸盐岩在埋藏成岩的不同温度压力条件下,酸性介质中溶解反应的吉布斯自由能均为负值,说明反应可自动向方解石、白云石溶解的方向进行,并随着温压的升高溶解的趋势增大.而且白云石溶解的趋势比方解石更大.碳酸盐岩溶蚀作用是受热力学规律支配的自然地质作用。碳酸盐岩溶蚀实验模拟的热力学数学模型对陕甘宁盆地油气田勘探具有重大的理论意义和实际应用价值。

       

      Abstract: The fifth member of the Lower Ordovician Majiagou Formation in the eastern and central areas of the Shaanxi-Gansu-Ningxia Basin as the carbonate reservoirs in-tercalated with the evaporite sediments in the tidal-flat facies consisting mainly of limestones,dolomite and gypsum(anhydrite)has undergone complex muhiphase dia-genesis,of which dissolution has an important effect on the study area.The present paper deals primarily with dissolution of the carbonate rocks in burial environments. The experiments of dissolution for dolomite were made at the temperatures of 75-130℃ and pressures of 20-30 MPa of burial diagenesis.The results have shown that the dissolution rates of dolomite inerease rapidly with the increasing temperatures and pressures.The temperature of 100℃ and pressure of 25 MPa are believed to be the most favourable conditions for dissolution of dolomite.It is estimated that the sec-ondary porosity created through dolomite dissolution in the deeper burial diagenetic environments should be more common than that formed in the epidiagenesis and shal-lower burial environments.Therefore the dolomite reservoirs in the deep-seated strata should be more ubiquitous than those in the shallow-seated strata.The analysis and calculation for the experimental results of carbonate dissolution in the burial environ-ments were also carried out for the first time based on the thermodynamic theory.The results of calculation have indicated that the limestones and dolomite can be dissolved in acetic acids at different temperatures and pressures of burial diagenesis,and the dis-solution of dolomite may occur more easily than limestones.The thermodynamic mod-el for experimental simulation of the dissolution of carbonate rocks has a great theo-retical significance and practical value in the prospecting and exploration of the oil and gas fields in the Shaanxi-Gansu-Ningxia Basin.

       

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